Crystalline modifications of tetra-(p-tolyl)antimony benzene sulfonate

Sharutin V.V.; Sharutina O.K.; Senchurin V.S.

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dc.contributor.author	Sharutin V.V.	en
dc.contributor.author	Sharutina O.K.	en
dc.contributor.author	Senchurin V.S.	en
dc.date.accessioned	2018-05-17T10:19:33Z
dc.date.available	2018-05-17T10:19:33Z
dc.date.issued	2013
dc.identifier.issn	360236
dc.identifier.other	https://link.springer.com/article/10.1134%2FS0036023613110181
dc.identifier.uri	http://dspace.susu.ru/handle/0001.74/18863
dc.description.abstract	Two structural isomers (I and II) have been obtained via the crystallization of tetra-(p-tolyl)antimony benzene sulfonate from toluene or water. The antimony atom in compound I has a distorted trigonal bipyramidal coordination to the carbon and oxygen atoms in axial positions (Sb-C, 2.097(11) (eq.), 2.103(10) (eq.), 2.111(10) (eq.), 2.139(10) (ax.) Å; Sb-O, 2.400(7) Å; OSbC, 176.9(3), CeqSbCeq, 115.3(4), 118.7(4), 119.1(4)). A crystal of compound II is built of tetrahedral tetra-(p-tolyl) stibonium cations (Sb-C, 2.097(2), 2.097(2), 2.105(2), 2.106(3) Å; CSbC, 104.68(9) -117.25(9)) and benzene sulfonate anions (S-O, 1.439(2), 1.451(2), 1.454(2) Å; OSO, 112.82(15) -113.70(16); OSC, 104.74(13) -105.78(12)). © 2013 Pleiades Publishing, Ltd.	en]
dc.language.iso	English
dc.relation.ispartof	Russian Journal of Inorganic Chemistry	en]
dc.subject	Antimony atoms	en]
dc.subject	Axial positions	en]
dc.subject	Compound I	en]
dc.subject	Crystalline modifications	en]
dc.subject	Oxygen atom	en]
dc.subject	Structural isomers	en]
dc.subject	Sulfonate anion	en]
dc.subject	Trigonal bipyramidal coordinations	en]
dc.subject	Isomers	en]
dc.subject	Antimony compounds	en]
dc.title	Crystalline modifications of tetra-(p-tolyl)antimony benzene sulfonate	en
dc.type	Article	en]
dc.identifier.doi	10.1134/S0036023613110181
dc.identifier.scopus	https://www.scopus.com/inward/record.uri?eid=2-s2.0-84889016748&doi=10.1134%2fS0036023613110181&partnerID=40&md5=34e741c3e377daca241a8ce1a69c6c2e