Synthesis and structure of triphenylbutyl phosphonium dodecatungstophosphate [(C6H5)3PC 4H9]3[PW12O40]

Sharutin V.V.; Sharutina O.K.; Senchurin V.S.

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dc.contributor.author	Sharutin V.V.	en
dc.contributor.author	Sharutina O.K.	en
dc.contributor.author	Senchurin V.S.	en
dc.date.accessioned	2018-06-18T09:24:17Z
dc.date.available	2018-06-18T09:24:17Z
dc.date.issued	2013
dc.identifier.issn	360236
dc.identifier.uri	http://dspace.susu.ru/handle/0001.74/19663
dc.description.abstract	The salt [(C6H5)3PC4H 9]3[PW12O40] has been synthesized by a reaction between triphenylbutyl phosphonium bromide and dodecatungstophosphoric heteropoly acid in water and structurally characterized. The phosphorus atoms in the two types of crystallographically independent [(C6H5)3PC4H9] + cations each have a distorted tetragonal coordination (P-C distances, 1.745(16)-1.823(15) Å; CPC angles, 107.2(8) -112.1(9)). In centrosymmetric [PW12O40]3- anions (with a phosphorus atom at the inversion center) the W-Oend, W-O(μ2), and W-O(μ4) bonds are 1.61(1)-1.71(2), 1.87(2)-1.94(2), and 2.44(2)-2.50(2) Å, respectively. © 2013 Pleiades Publishing, Ltd.	en]
dc.language.iso	English
dc.relation.ispartof	Russian Journal of Inorganic Chemistry	en]
dc.subject	Centrosymmetric	en]
dc.subject	Heteropoly acids	en]
dc.subject	Inversion center	en]
dc.subject	Phosphorus atom	en]
dc.subject	Complexation	en]
dc.subject	Synthesis (chemical)	en]
dc.title	Synthesis and structure of triphenylbutyl phosphonium dodecatungstophosphate [(C6H5)3PC 4H9]3[PW12O40]	en
dc.type	Article	en]
dc.identifier.doi	10.1134/S0036023613120206
dc.identifier.scopus	https://www.scopus.com/inward/record.uri?eid=2-s2.0-84891817485&doi=10.1134%2fS0036023613120206&partnerID=40&md5=998a0d6f5397da2c99ebab84cd742510